It is a weak, diprotic, reducing acid, readily soluble in water and dispersed into the air by winds when emitted from natural, industrial, and anthropogenic sources. Effect of oxygen and hydrogen sulfide on carbon dioxide. For over 50 years the standard way to deal with odors entering wastewater treatment plants was to prechlorinate the influent sewers. Inhibition of hydrogen sulfide corrosion of steel by. Hydrogen sulfide corrosion in lowno x combustion systems. It is a constituent of natural gas, petroleum, sulfur deposits, volcanic gases and sulfur springs. Hydrogen sulfide is the chemical compound with the formula h 2 s. In the context of h2s corrosion of mild steel, the direct electrochemical reduction of h2s. Because of the initial low flow and the long distance hence a long retention time of approximately 30 days in the pipe, the wsa was concerned about the generation of hydrogen sulfide gas in the force main and microbialinduced corrosion. The duration must be long enough to allow the stable crystallographic forms of metal sulfide to form. It can occur when carbonsteel equipment becomes exposed to wet h 2 s service environments, and it can come in several different forms.
Wet h 2 s corrosion can be a particularly dangerous form of corrosion because damage. Oxidation of hydrogen sulfide and corrosion of stainless steel in gas mixtures containing h2s, o2, h2o. Pdf sulfide stress corrosion cracking and hydrogen induced. File sharing on the engtips forums is outsourced to. The corrosion behavior also depends on the state of the metal surface. Hydrogen sulfide gases are generated within the anaerobic slime layer formed on the submerged pipe walls. Lower, longerterm exposure can cause eye irritation, headache, and fatigue. Hydrogen induced cracking of low strength steels in geothermal fluids keith a. Hydrogen sulfide corrosion in sanitary sewers effected by flow velocities the reduction, elimination, or control of hydrogen sulfide h 2s should be the goal of all designers of sanitary sewer systems. Pdf corrosion rates of steel alloys were investigated in gas oil and its mixture with waste cooking oil and animal waste lard over 1, 3, 7 and. Mechanism of sulfide corrosion hydrogen sulfide corrosion can occur by two mechanisms. All atsdr toxicological profile pdf files are electronic conversions from paper copy or other electronic ascii text files.
Hydrogen sulfide h2s, in anaerobic and aerobic forms, has the capacity to severely. Sep 26, 2019 toxicological profile for hydrogen sulfide carbonyl sulfide. Normally, when h2s corrosion is a severe problem, one of these other gases is present. Most hydrogen sulfide in the air comes from natural sources. Inhibition of hydrogen sulfide corrosion of steel by volatile. The corrosionelectrochemical behavior of both carbon steel and aluminum alloys in hydrogen sulfidebearing mineralized media is considered. How to avoid sewer stench and corrosion water online. Corrosion investigation of pipeline steel in hydrogen. This reaction can result in deep pitting of iron or steel. Hydrogen sulfide stress corrosion cracking in materials. Hydrogen can also be absorbed by metal during aqueous corrosion or cathodic charging. It occurs naturally in crude petroleum, natural gas, and hot springs. Wet hydrogen sulfide h2s cracking inspectioneering. As a result, sulfate conversion and dissolved sulfide production is also greatly increased.
Hydrogen sulfide is often produced from the microbial breakdown of organic matter in the absence of oxygen gas, such as in swamps and sewers. Under lownox substoichiometric combustion conditions, sulfur in coal is released mostly as h2s gas, which will sulfidize boiler tubes at furnacewall temperatures. Effect of carbon dioxide and hydrogen sulfide on the localized corrosion of. It is produced in nature primarily through the decomposition of organic matter by bacteria. Hydrogen sulfide results aegl program acute exposure. The concrete corrosion products were suspended in an acidic solution, mimicking the conditions in the pore water of corroded concrete. Department of health and human services, public health service. Hydrogen sulfide corrosion in wastewater collection and. Pdf hydrogen sulphide corrosion of carbon and stainless steel. Hydrogen induced cracking of low strength steels in.
However, there are ways to interrupt the sulfide cycle, reduce dissolved sulfide concentration, avoid h2s gas release, and prevent corrosion as discussed below. Hydrogen sulfide aegl technical support document pdf 70 pp, 493 k contact us to ask a question, provide feedback, or report a problem. Table of contents acknowledgement i disclaimer ii 1. Hydrogen sulfide is a colorless gas and has a strong odor of rotten eggs hsdb, 1998. In addition, hydrogen sulfide is produced by bacterial breakdown of organic materials and. Indoor air concentrations of hydrogen sulfide was significantly higher in homes reporting drywall related complaints with a mean concentration of 0. Description of the hydrogen sulfide induced corrosion of concrete sew er systems a new approach. Sanitary wastes contain a variety of organic and sulfur compounds. Susceptible alloys, especially steels, react with hydrogen sulfide, forming metal sulfides and atomic hydrogen as corrosion byproducts. Lichti, david m firth and annette d karstensen mpt solutions, po box 310, lower hutt, new zealand k. This research paper is aimed at investigating the corrosion rate of steels in water and h2s. The reduction, elimination, or control of hydrogen sulfide h2s should be the goal of all designers of sanitary sewer systems.
Hydrogen sulfide corrosion and its prevention is an important topic in a range of industrial processes and environments including oil and gas and its related activities. The influence of hydrogen sulfide on corrosion of iron. Silver is commonly used in the manufacture of surfacemounted electrical components such as chip resistors but is susceptible to silver sulfide formation when exposed to certain sulfurbearing gaseous environments. It should not be confused with the term stress corrosion cracking which is an anodic cracking mechanism. Biogenic sulfide corrosion is a form of corrosion that is caused by sulfuric acid, which in turn is created by bacteria.
High temperature hydrogen sulfide corrosion corrosion. Download limit exceeded you have exceeded your daily download allowance. Some common names for the gas include sewer gas, stink damp, swamp gas and manure gas. Aug 25, 2017 biogenic sulfide corrosion is a form of corrosion that is caused by sulfuric acid, which in turn is created by bacteria. Atsdr toxic substances hydrogen sulfide carbonyl sulfide. Consumer product safety commission conducted an emission and corrosion study of 51 homes. Hydrogen sulfide corrosion of carbon and stainless steel alloys in mixtures of renewable fuel sources under coprocessing conditions article pdf available in modern applied science 124.
S gas release from piping corrosion failure near a weld. Hydrogen sulfide h s gas release from piping corrosion. Prediction of co2 and h2s emissions from wastewater wet wells. Listed below are few methods available to control the rate of hydrogen sulfide corrosion. Detection, control, and correction of hydrogen sulfide. The atmospheric corrosion of copper by hydrogen sulphide. Hydrogen sulfide h2s is aggressive gas, provoking acid corrosion, which in. Hydrogen sulfide corrosion sour corrosion drilling fluids. Pdf sulfide stress corrosion cracking and hydrogen. The extent of corrosion depends on the asset type, materials, system design and operational decisions.
Biogenic sulfide corrosion is a bacterially mediated process of forming hydrogen sulfide gas and the subsequent conversion to sulfuric acid that attacks concrete and steel within wastewater environments. Hvac design considerations for corrosive environments. Aug 26, 2016 abstract rbonyl sulfide cos, which occurs as an impurity in commercial sources fo propane can hydrolyze in the presence of water to form hydrogen sulfide h2s and carbon dioxide cos is not itself corrosive, the hydrolysis product h2s is corrosive, especially in the presence of water. Water 7732185 persistence and degradability not established. Copper corrosion by atmospheric pollutants in the electronics. Hydrogen sulfide h2s is aggressive gas, provoking acid corrosion, which in this case is called the hydrogen sulfide corrosion. Hydrogen sulphide h 2 s is considered one of the most corrosive atmospheric pollutants. Hydrogen sulfide occurs naturally and is also produced by human activities. Hydrogen sulfide is soluble in certain polar organic solvents, notably methanol, acetone, propylene carbonate, sulfolane, tributyl phosphate, various glycols, and glycol ethers hsdb, 1998. The hydrogen sulfide gas is biochemically oxidized in the presence of moisture to form sulfuric acid. Corrosion of metal and concrete is a major issue associated with the generation and oxidation of hydrogen sulfide.
Hydrogen sulfide attack and corrosion of copper electrical. This can happen during pickling and electroplating of metal. Hydrogen sulfide h 2 s can either accelerate or inhibit corrosion of iron under different experimental conditions. Formation of silver sulfide in an electrical component often results in its malfunction or failure. The bare copper tubing was split in half to reveal the extent of internal corrosion as a result of natural gas flow during the 52week exposure period. For convenience and flexibility, however, chemical oxidation using hydrogen peroxide h 2 o 2 continues to grow in its scope of application. The main components formed at the surface of the samples are copper oxides and sulphide. Hydrogen sulfide is a colorless, flammable, extremely hazardous gas with a rotten egg smell. This substance has been found in at least 24 of the 1,467 national priorities list sites identified by the environmental protection agency epa.
The interior surface of the sample exhibited a coating of. An increase in the partial pressure of hydrogen sulfide aggravates the catastrophic breakdown of carbon steel, yet diminishes both the corrosion rate and the localization of corrosion attack on aluminum alloys. Hydrogen sulfide 7783064 final level of odor awareness 0. Corrosion behavior of aluminum alloys in the presence of. Alloys which are commercially available and those which have modified metallurgical structures and. The chemical mechanism of this type of corrosion can be simply, though not completely, stated as. Some people can smell hydrogen sulfide at very low levels, as low as 0. Do you have any experience suggestion regarding which material is the more suitable. Microbial induced corrosion mic has been increasingly evident in concrete manholes and related sanitary sewer structures for decades.
Carbon steel and type 304 stainless steel have reasonably good corrosion resistance up to 700 f 371 c and 900 f. Prediction of co2 and h2s emissions from wastewater wet. Corrosion of cu in the presence of air, h 2 s, and humidity produces oxides andor sulphides as wet films leading to electrical failures in electronic equipment. The saturation of model seawater with hydrogen sulfide decreases the corrosion rate of 20 steel by a factor of. Hydrogen sulfide attack and corrosion of copper 2003. Dunlop named this type of eac sulfide corrosion stress cracking scsc, which is now an obsolete term. Since the discovery and development of oil and gas fields containing hydrogen sulfide in the production wells, the problem of protection of metal from the hydrogen sulfide corrosion arose acutely. Hydrogen sulfide burns in oxygen with a blue flame to form sulfur dioxide so 2 and water. Hydrogen sulfide control headworks odor control with hydrogen peroxide michael fagan and john r. Oxidation of hydrogen sulfide and corrosion of stainless steel in gas. Copper tubing evaluation in a natural gas environment.
Pdf hydrogen sulfide corrosion of carbon and stainless steel. It is proved that co2 corrosion of carbon steel increases by 1. The corrosion rates of various alloys and coatings in simulated substoichiometric combustion gas were studied. From our knowledge of the microbiology and electrochemistry of anaerobic corrosion by sulfatereducing bacteria, any realistic test must meet certain conditions. Sulfide and odor control for headworks with h2o2 usp. Acidic gases, such as hydrogen sulfide, sulfur oxides, chlorine, hydrogen fluoride hf and nitrogen oxides. Pdf in accordance with modern regulations and directives, the use of renewable biomass materials as precursors for the production of fuels for. It is a pollutant with a high level of toxicity impairing human health and the environment quality. Laboratory evaluation of materials for resistance to. Oxidizing gases, such as ozone of the gases that can cause corrosion, the acidic gases are typically the most harmful. Tin and silver plating of copper components have been suggested to protect the copper. Formation of silver sulfide in an electrical component often results in. Josop 500 hydrogen sulfide program and procedure 4 than air and collects in lowlying, enclosed and poorly ventilated areas such as basements, manholes, underground telephone vaults, and confined spaces. Pdf hydrogen sulfide corrosion of weld regions in api.
W is the weight loss mg, d is specimen density g cm3, a is specimen exposure surface in 2 and t is exposure time h na 2 s. Mild steel is a popular structural steel in this industry but is susceptible to surface scale formation and associated corrosive action, the prevention of which requires some. Sulfide stress cracking ssc is a form of hydrogen embrittlement which is a cathodic cracking mechanism. Pdf hydrogen sulfide corrosion of carbon and stainless. When corrosion occurs in a lowph solution, some of the reduced hydrogen does not form h2, but instead, diffuses into the metal as atomic hydrogen. Mic occurs when sulfuric acid, generated from raw sewage, reacts with the properties of cement to diminish the integrity of concrete manhole bases and related structures. Hydrogen sulfide is a colorless gas with a rottenegg odor. The influence of hydrogen sulfide on corrosion of iron under. Hydrogen peroxide, to 30% g g f nr nr nr 150 100 150 g nr g g f hydrogen sulfide, to 5%nr f g nr nr g 180 210 210 f nr g g nr lactic acid nr f f nr nr f 210 210 210 nr nr g g magnesium carbonate f g f f f g 180 180 g. March 2016 jan 2020 it is ardent policy that employees shall not knowingly work on, open, or participate in anyway in operations that involve systems known to contain hydrogen sulfide h 2 s until the system has been declared.
Hydrogen sulfide is a chemical compound with the formula h 2 s, and is often a colorless gas with a rotten egg odor, commonly referred to as sewer gas. The atmospheric corrosion of copper by hydrogen sulphide has been followed during field tests using different sulphide concentrations, for 77 days, and during exposure to a welldefined synthetic atmosphere in a test chamber. Biogenic sulfide corrosion attacks materials such as steel and concrete. We have electrical equipment exposed to low levels of hydrogen sulfide at a waste treatment plant. Hydrogen sulfide corrosion acidic environments hzs as well as co2 can be dissolved in aqueous environments to form acidic, corrosive solutions see figure 1. Control dissolved sulfide through chemical addition. Depending on the temperature, pressure, and ph of the environment, aqueous environments containing. At low concentrations it has an obnoxious odor similar to rotten eggs. The test rig study on hydrogen sulfide corrosion of concrete sewers revealed that hydrogen sulfide absorption and oxidation is a fast process compared to hydrogen sulfide release from the bulk water of a gravity sewer, and that corroding concrete is capable of oxidizing hydrogen sulfide at rates similar to submerged sewer biofilms. The effect of sulfuric acid on concrete and steel surfaces exposed to severe wastewater. Hydrogen sulfide burns with a blue flame to form sulfur dioxide which is also a toxic gas. S gas release occurred from a piping corrosion failure near a weld, on the 8inch side of an 8inch by 4inch reducer on the blowdown line for a thirdstage section. On the other hand, corrosion of cu occurs when the rh overpasses the 80% and the so 2 concentration is larger than 0. Biogenic sulfide corrosion is commonly a problem in the water and wastewater industry.
As seen in figure 1, cracking was observed only on the tension side of ubend samples. Corrosion of concrete sewersthe kinetics of hydrogen sulfide. What h 2 s has done to both the anodic iron dissolution and cathodic hydrogen evolution, in most cases, is to have a strong acceleration effect, causing iron to be seriously corroded in acidic medium, but h 2 s can also have a strong inhibition on the iron corrosion under. High temperature hydrogen sulfide corrosion of carbon steel and low chrome alloys has become a serious problem in the petroleum industry in connection with the increasing use of high pressure hydrogenation and dehydrogenation processes for upgrading petroleum fractions. Jul 31, 2014 as a result, sulfate conversion and dissolved sulfide production is also greatly increased. Just a few breaths of air containing high levels of hydrogen sulfide gas can cause death. Different concentrations of h 2 s containing solution were made as shown in table 2. Document no s ossspp0074 hydrogen sulfide h2 revision. Silver sulfide corrosion control using corrosion prevention. Wet h 2 s corrosion can be a particularly dangerous form of corrosion because damage caused by it takes place on the interior of.
The gas can be dispersed by wind movement or air currents. Abiotic and biotic oxidation of hydrogen sulfide related to concrete corrosion was studied in corrosion products originating from a sewer manhole. Sulfide stress corrosion cracking and hydrogen induced cracking of a216wcc wellhead flow control valve body article pdf available in case studies in engineering failure analysis. It is a colorless chalcogen hydride gas with the characteristic foul odor of rotten eggs. The removal of hydrogen sulfide and dissolved oxygen was measured in parallel in the suspension, upon which the.
Modeling of hydrogen sulfide oxidation in concrete. Carbonyl sulfide pdf, 112kb quick reference guide providing information such as chemical and physical properties, sources of exposure, routes of exposure, minimal risk levels, childrens health, and health effects for a substance. Current osha standard for h2s osha pels based on 1960s data general industry. Latest news, games, resources, videos and job postings for engineers. Additional characteristics are provided in appendix i in this program. Hydrogen sulfide corrosion and its prevention is an important topic in a range of industrial processes and environments including oil and gas and its related. Walton, usp technologies formerly us peroxide march 17, 1999. Protection of metal from the hydrogen sulfide corrosion. S concentration, relative humidity and air temperature on concrete sewer corrosion.